JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 48

FEATURE
matrix

Novel thermoset composites for more
competitive and sustainable industries

Dr. Alaitz Rekondo,
Head of Polymers and composite
Dr. Gemma Vara,
Technical Marketing Head
Cidetec Surface Engineering

A

particularly useful approach to
generate reprocessable and recyclable
thermosets is the introduction of
reversible or exchangeable bonds into the
polymer network. The idea behind this is to
be able to reconnect the chemical crosslinks
that are broken when a material fractures,
restoring the material's integrity. The dynamic hardener used to formulate 3R epoxy
resins contains a reversible chemical bond
(aromatic disulphide) that can be rearranged
under a determined external stimulus such
as temperature or the exposure to a specific
chemical agent after its complete cure. This
rearrangement capacity of the aromatic disulphide bond enables the reprocessing, repairing and recycling of 3R Composites. 3R
resins and composites are easily formulated
from readily-available commercial products.
When produced for the first time, 3R
Composites can be processed just like
traditional composites, as the resin viscosity
and curing temperatures can be adjusted to

48

Being aware that the thermoset composite materials sector
needs processes that allow higher production rates and a recycling solution, CIDETEC Surface Engineering started studying
dynamic covalent chemistries in 2013, resulting in the development and patenting of a thermo-mechanically reprocessable
epoxy resin and its composites that preserve all the advantages
of conventional thermosets while showing unprecedented features such as re-processability, repairability and recyclability.
The new material was named 3R Composite.

the process requirements. Thus, the 3R resin
has already been adapted for use in RTM,
infusion and pultrusion technologies.
Reprocessability
Once 3R Composites are cured, reshuffling
of the dynamic crosslinks can be promoted
at high temperatures (typically 200-220°C).
This permits innovative processes to be
carried out, such as thermoforming of
fully-cured laminates, using conventional
thermoplastic compression moulding and
thermoforming processes. As a result, 3R
Composites allow faster and more automated production rates when compared to
conventional methods.
Repairability
Similarly, easy repair of resin/fibre delaminations and resin micro-cracks is possible
by simply applying heat and pressure to the
damaged part. Repairing parts delaminated
either during the manufacturing process or
in service, which are currently rejected due
to high costs, is also possible.

jec composites magazine / N°136 September - October 2020

3R-thermoforming

Recyclability
Two different routes can be considered for
recycling 3R Composites. The first one is
the chemical route. The dynamic network
can be completely disrupted by exposure
to a specific chemical reagent, which exchanges bonds with the dynamic network,
the resin being totally dissolved without
affecting the reinforcement. The clean fibres
remain continuous as they are not degraded
by the reagent used to dissolve the resin. In
addition, the resin can also be recovered and
re-used. It should be noted that the 3R resin
shows the same good chemical resistance
as conventional thermoset composites to



JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020

Table of Contents for the Digital Edition of JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020

Cover
Edito
“We can change the way we envision global shipping overall”
Contents
NEWS
In brief
Agenda
BUSINESS
Reinforcement - Natural-fibre composites: an overview
Startup - When 3D printing meets sustainability
China - Xinzhou bets on the bamboo-based composites industry
MANUFACTURING
Wind - lnnovation in wind power through multi-process-capable systems
Automation - Higher production capacity thanks to automated manufacturing
FEATURE Sustainability - The path has been plotted
Recycling ecosystem - Composites recycling: in search of the circular economy
Mobility - A new generation of recycled composite materials for sustainable mobility
Preimpregnated textile - Healable composites to improve circularity
Process - New trends in composites and plastics recycling
Raw materials - Innovative composites made from up to 92% reclaimed materials
Construction - Biocomposites and automation: a sustainable future for the building industry
Ressources - Waste-free composite wheel production
Wind energy - From bottle to blade
Durable composites - Upcycling plastic bottles into value-added composite applications
Matrix - Novel thermoset composites for more competitive and sustainable industries
SOLUTIONS
Aerospace - Slinging rockets into space
Aerospace - Composites push back the final frontier
Railway - Composite overhead line catenary system for light rail
TECHNOLOGY
Repair - Developing an eddy current-based sensor system for quality assurance of carbon fibres
Inside the lab - Advanced Composite Materials Facility University of Southampton
Resin - Development of new type of plastics: Polypropylene 2.0
Index
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JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Cover
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 2
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Edito
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - “We can change the way we envision global shipping overall”
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 5
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Contents
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 7
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - In brief
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 9
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 10
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Agenda
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Reinforcement - Natural-fibre composites: an overview
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 13
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Startup - When 3D printing meets sustainability
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 15
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - China - Xinzhou bets on the bamboo-based composites industry
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 17
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Wind - lnnovation in wind power through multi-process-capable systems
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 19
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 20
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 21
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Automation - Higher production capacity thanks to automated manufacturing
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 23
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 24
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 25
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Recycling ecosystem - Composites recycling: in search of the circular economy
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 27
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 28
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 29
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 30
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Mobility - A new generation of recycled composite materials for sustainable mobility
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 32
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Preimpregnated textile - Healable composites to improve circularity
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 34
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 35
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Process - New trends in composites and plastics recycling
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 37
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Raw materials - Innovative composites made from up to 92% reclaimed materials
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 39
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Construction - Biocomposites and automation: a sustainable future for the building industry
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 41
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Ressources - Waste-free composite wheel production
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 43
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Wind energy - From bottle to blade
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 45
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Durable composites - Upcycling plastic bottles into value-added composite applications
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 47
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Matrix - Novel thermoset composites for more competitive and sustainable industries
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 49
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 50
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Aerospace - Slinging rockets into space
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 52
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 53
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Aerospace - Composites push back the final frontier
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 55
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Railway - Composite overhead line catenary system for light rail
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 57
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 58
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Repair - Developing an eddy current-based sensor system for quality assurance of carbon fibres
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 60
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 61
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Inside the lab - Advanced Composite Materials Facility University of Southampton
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 63
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Resin - Development of new type of plastics: Polypropylene 2.0
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 65
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - Advertisers
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 67
JEC COMPOSITES MAGAZINE - Issue #136 - September/October 2020 - 68
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