JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 141

Properties and composite applications of nanocalcite-modified epoxies

Tab.2: Resin property data: MR 8831, 8832, 8834 (anhydride cure) and 8835 (dicy cure). Standard deviations in parentheses. Tg by DMA E' onset
Property

ASTM test

MR 8831

MR 8832

Control for MR
8831, 2

MR 8834

Control for MR
8834

MR 8835

Control for MR
8835

35

37

0

39

0

48

0

Wt% calcite
Density (g/cc)

Calculated

1.4

1.4

1.2

1.5

1.2

1.6

1.2

Tg (°C)

E1640

118

125

131

220

220

118

142

Tensile
modulus (GPa)

D638

5.0
(0.1)

4.5
(0.3)

3.17
(0.05)

5.6
(0.1)

3.1
(0.1)

6.6
(0.1)

2.8

Fracture toughness (MPa√m)

D5045

0.79
(0.08)

1.67
(0.06)

0.57
(0.06)

0.62
(0.05)

0.52
(0.04)

0.71
(0.06)

0.74
(0.02)

Barcol
hardness (HB)

D2583

51
(0.6)

55
(0.6)

33
(0.9)

60 (0.9)

39
(0.8)

55 (0.6)

30
(0.7)

Linear cure
shrinkage (%)

D2566

0.33

0.34

0.51

0.32

0.52

0.28

0.54

Cure exotherm
(J/g)

D3418

155

171

271

150

250

300

557

CTE (µm/m°C)

E831

36

46

58

41

61

40

58

Tab.3: Static glass-fabric laminate data for MR 8835 and control matrix resins
Property

ASTM test method

MR 8835

Control

% change

0° compression modulus (GPa)

D6641

31.6

20.3

56

0° compression strength (MPa)

D6641

434

332

31

Through-thickness compression modulus (GPa)

D695

7.65

4.96

54

Through-thickness compression strength (MPa)

D695

696

455

53

Punch shear strength (MPa)

D732

192

128

50

Through-thickness CTE (µm/(m°C))

E831

28.5

40.8

-30

in resin modulus. Nanoparticle modification of epoxies offers an attractive solution to the stiffness/toughness problem.

Translation of nanocalcite epoxy properties
into composite laminate properties: MR 8835
As mentioned in the introduction, an important outcome of nanoparticle resin modification is the translation of these improved neat

resin properties into enhancements in fibre-reinforced systems.
Thus, the effect of nanocalcite-modified epoxy matrix resins on the
mechanical properties and tensile fatigue performance of glass-reinforced composites was examined [12]. Glass fabric-reinforced composite laminates were created using an industry-standard epoxy matrix as a control material and 3M Matrix Resin 8835 (MR 8835), an
epoxy resin with a high loading of surface-functionalized nanoscale

Fig. 2: Tensile stress-strain behaviour
for composite laminates showing the
low-strain region. Examples of strain
differences at arbitrarily-chosen
stresses are shown

N°133 March - April 2020

/ jec composites magazine

141



JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020

Table of Contents for the Digital Edition of JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020

Cover
Edito
“For the past 130 years, every aspect of tire performance has been improved, except for one”
Contents
NEWS
In brief
Agenda
Aerospace
BUSINESS
Strategy - Selling your business, Part 1: maximizing value on both sides of the deal
Trends - Automotive: what will be tomorrow’s reality?
Boatbuilding - Maritime and shipbuilding sector: a niche market with growth potential
China - China’s glass fibre industry is entering a new cycle
MANUFACTURING
Fabrics - GaplessWeave process for higher-quality carbon fibre fabrics
Electric vehicle - The potential of epoxy SMC in electro-mobility battery systems
Simulation - New updates for the Composite Materials Module’s users
Aerospace - lnfused primary structures: the gateway to tomorrow’s air mobility
Aircraft interiors - New core filler for aircraft interiors: reduced material, weight and manufacturing costs
Sustainability - Eco Impact Calculator, a Life Cycle Assessment tool for the composites industry
PREVIEW JEC WORLD 2020
- EDUCATION & KNOWLEDGE
- MARKET OVERVIEW / Fact & figures
- AT THE FOREFRONT IN JEC WORLD 2020
- VIEW FROM THE TOP
- INNOVATION
- SUSTAINABILITY
- END-USE MARKETS
- PROCESS & AUTOMATION
- INTERNATIONAL
SOLUTIONS
Book - Composites in infrastructure
Construction - Composites joining science and religion
Urban equipment - Composite infrastructure products: a new alternative for the construction industry
Aeronautics - To new horizons, with composites
Aeronautics - Thermoplastic composite bracket for aircraft engines
Off shore wind energy - Taming the offshore winds
Biocomposites - Where are natural fibre composites heading?
Natural fibres - The challenges of building large structures from flax fibre composite
TECHNOLOGY
Resin - Properties and composite applications of nanocalcitemodified epoxies
Inside the lab - Architected Material and Structures (AMS), a team from Navier Laboratory (Ecole des Ponts ParisTech/IFSTTAR/CNRS)
FMEL - Fibre-metal elastomer laminates – Lightweight components with superior damping characteristics
Index
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JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - CF
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - CB
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Cover
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 2
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Edito
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - “For the past 130 years, every aspect of tire performance has been improved, except for one”
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 5
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Contents
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 7
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - In brief
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 9
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 10
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Agenda
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Aerospace
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 13
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Strategy - Selling your business, Part 1: maximizing value on both sides of the deal
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 15
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 16
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Trends - Automotive: what will be tomorrow’s reality?
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 18
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 19
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Boatbuilding - Maritime and shipbuilding sector: a niche market with growth potential
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 21
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - China - China’s glass fibre industry is entering a new cycle
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 23
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 24
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Fabrics - GaplessWeave process for higher-quality carbon fibre fabrics
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 26
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 27
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 28
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Electric vehicle - The potential of epoxy SMC in electro-mobility battery systems
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 30
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 31
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Simulation - New updates for the Composite Materials Module’s users
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 33
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Aerospace - lnfused primary structures: the gateway to tomorrow’s air mobility
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 35
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 36
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Aircraft interiors - New core filler for aircraft interiors: reduced material, weight and manufacturing costs
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 38
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Sustainability - Eco Impact Calculator, a Life Cycle Assessment tool for the composites industry
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 40
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 41
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 42
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 43
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 44
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - EDUCATION & KNOWLEDGE
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 46
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - MARKET OVERVIEW / Fact & figures
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - AT THE FOREFRONT IN JEC WORLD 2020
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 49
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 50
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 51
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - VIEW FROM THE TOP
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 53
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 54
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 55
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - INNOVATION
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 57
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 58
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 59
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JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 68
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 69
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - SUSTAINABILITY
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 71
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - END-USE MARKETS
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 73
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 74
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 75
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 76
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 77
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 78
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 79
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - PROCESS & AUTOMATION
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 81
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 82
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 83
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 84
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JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 86
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JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 89
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 90
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - - INTERNATIONAL
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 92
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 93
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 94
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JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 113
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 114
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Book - Composites in infrastructure
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 116
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 117
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Construction - Composites joining science and religion
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 119
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 120
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 121
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Urban equipment - Composite infrastructure products: a new alternative for the construction industry
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 123
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Aeronautics - To new horizons, with composites
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 125
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 126
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Aeronautics - Thermoplastic composite bracket for aircraft engines
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 128
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Off shore wind energy - Taming the offshore winds
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 130
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 131
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 132
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Biocomposites - Where are natural fibre composites heading?
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 134
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 135
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Natural fibres - The challenges of building large structures from flax fibre composite
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 137
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 138
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Resin - Properties and composite applications of nanocalcitemodified epoxies
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 140
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 141
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 142
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JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 146
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 147
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Inside the lab - Architected Material and Structures (AMS), a team from Navier Laboratory (Ecole des Ponts ParisTech/IFSTTAR/CNRS)
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 149
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 150
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - FMEL - Fibre-metal elastomer laminates – Lightweight components with superior damping characteristics
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 152
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - 153
JEC COMPOSITES MAGAZINE - Issue #133 - March/April 2020 - Advertisers
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