JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 43

Fig. 3: FGS (functionalised Graphene Sheets) improves the Young's Modulus of
Epoxy up to a certain point ~ 0.1wt%. But adding more than this does not make
any more improvements [9]

A similar trend is also seen with another property called fracture
toughness (the resistance of the material to cracking). Structural polymers such as epoxies typically have low fracture toughness and are
inherently brittle. By modifying plastics using graphene, the polymer
could have a better fracture resistance. The theory behind this is that
cracks growing through a polymer will be blocked or diverted around
flakes of graphene. Since several million flakes of graphene can be
crammed into a cubic centimetre of polymer, the overall diversion
a crack path could take would be massive. This would create a more
damage tolerant material.
In [9], 0.125 wt% of oxygen-functionalised graphene increased the
fracture toughness of epoxy by 65%. In another paper, using 0.5
wt% of oxygen-functionalised graphene produced a 40% increase in
fracture toughness which outperformed both GNP and MWNT [10].
The best results regarding mechanical property improvements have
been when graphene is functionalised with oxygen atoms. The
oxygen atoms are thought to provide a better adhesion to the matrix
and a better stress transfer. One problem with oxygen functionalisation is that it disrupts the electrical conductivity of graphene,
which no longer becomes highly conducting. Therefore, creating
an electrically-conductive composite at the same time as improving
mechanical properties may be difficult. However, a compromise can
be reached if the amount of functionalisation can be controlled.
Electrically-conductive composites can be created by making the
flakes of graphene form a conductive pathway through the polymer.
To do this, the graphene flakes must touch at least one other to carry
the charge from one flake to another. At the same time, the flakes
must resist agglomeration. The conductivity of polymers can be
enhanced by several orders of magnitude, from 10-14 S m-1 to ~ 10-1 S
m-1, using up to 1 wt% GNPs. But the conductivity reaches a plateau
when more GNPs are added [11]. Research is required to overcome
this barrier.
Unlike electrical conductivity, thermal conductivity is one area
where the improvements continue even when using higher additions
of graphene [12] (see Figure 5). This seems a promising area with
graphene outperforming graphite and carbon black.

Fig. 4: Improvement of electrical conductivity in a polycarbonate matrix. Conductivity increases quickly at first but soon levels off. This trend is seen in all polymers [11]

Fig. 5: Thermal conductivity improves linearly when you add more graphene to
epoxy. MLG = MultiLayer Graphene (up to 5 layers of graphene stacked on top of
one another) [12]

No99 September 2015 /

jec composites magazine 43



Table of Contents for the Digital Edition of JEC COMPOSITES MAGAZINE - Issue #99 - September 2015

Cover
Edito
Point of view: The future of mass production
Contents
Companies & Business
In brief
Interview UCI - “Our aim is to ensure bicyclers are safe to race”
Agenda of Events
Applications
Recreational aviation - A recreational airplane as advanced as the latest widebodied aircraft
Sports & leisure - Cork, flax and green epoxy: a perfect balance for a skateboard
Medical - Lightweight emergency medical cot
Market
Natural fibres - Tending towards optimism
SPECIAL JEC FORUMS
Interview - MIT-NECST Lab: a research consortium dedicated to composites in Aeronautics
Conferences - Gain insight into the JEC 2015 Forums conferences programme
FEATURE WIND ENERGY
Wind energy - Double-digit growth continues
Design - A wind turbine without blades
Simulation - Visualizing RTM behaviour using advanced 3D CAE technology
Permeability - Optimizing fabrics for wind blade infusion
Automation - Automation strategies in rotor blade production: preforming vs. direct textile layup
Recycling - Recycling decommissioned composite wind blades
Platform - An internet aid for advances in wind turbine blade design
Research & Development
Graphene - Gambling with graphene, will it pay off ?
Thermal expansion - Boeing simulates thermal expansion in composites with expanded metal foil for lightning protection of aircraft structures
Technology & Innovations
Heating - Power transfer in complex shape heated moulds or functional composites
Manufacturing - Tension control in composites manufacturing
3D printing - A fully biodegradable flax fibre-reinforced thermoplastic filament for 3D printing
RTM/LCM - Fast production epoxies for lightweight automotive composites
Index
In the world
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Cover
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 2
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Edito
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Point of view: The future of mass production
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 5
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Contents
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 7
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - In brief
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 9
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 10
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Agenda of Events
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Interview UCI - “Our aim is to ensure bicyclers are safe to race”
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 13
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Recreational aviation - A recreational airplane as advanced as the latest widebodied aircraft
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 15
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Sports & leisure - Cork, flax and green epoxy: a perfect balance for a skateboard
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Medical - Lightweight emergency medical cot
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 18
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Natural fibres - Tending towards optimism
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 20
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 21
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Interview - MIT-NECST Lab: a research consortium dedicated to composites in Aeronautics
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 23
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Conferences - Gain insight into the JEC 2015 Forums conferences programme
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 25
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Wind energy - Double-digit growth continues
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 27
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Design - A wind turbine without blades
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Simulation - Visualizing RTM behaviour using advanced 3D CAE technology
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 30
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 31
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 32
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Permeability - Optimizing fabrics for wind blade infusion
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 34
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Automation - Automation strategies in rotor blade production: preforming vs. direct textile layup
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 36
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 37
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Recycling - Recycling decommissioned composite wind blades
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Platform - An internet aid for advances in wind turbine blade design
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 40
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Graphene - Gambling with graphene, will it pay off ?
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 42
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 43
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 44
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Thermal expansion - Boeing simulates thermal expansion in composites with expanded metal foil for lightning protection of aircraft structures
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 46
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 47
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Heating - Power transfer in complex shape heated moulds or functional composites
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 49
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 50
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 51
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Manufacturing - Tension control in composites manufacturing
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 53
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 54
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 55
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 56
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 57
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 58
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 3D printing - A fully biodegradable flax fibre-reinforced thermoplastic filament for 3D printing
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 60
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 61
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - RTM/LCM - Fast production epoxies for lightweight automotive composites
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 63
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 64
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - Index
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - In the world
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 67
JEC COMPOSITES MAGAZINE - Issue #99 - September 2015 - 68
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