JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 58

KNOW-HOW Environment g…/… FRP recycling technology using sub-critical water hydrolysis A molecular structure analysis of the SFC extracted from the reaction liquid was conducted by NMR and GPC. The NMR analysis showed that the styrene/fumaric acid ratio was 2.2:1. The GPC analysis indicated that its molecular weight was approximately 30,000. Enhanced recycling of the styrenefumaric acid copolymer Although the SFC’s molecular structure is similar to that of the LPA, the carboxylic acid group in the SFC needs to be modified to develop the shrinkage control effect. A modification reaction using benzyl chloride with tetra-nbutyl ammonium bromide as catalyst was conducted at 90° C for 8 hours. A modified SFC, styrene-benzyl fumarate copolymer (SBFC), was obtained after esterification as shown in figure 6. process (figure 7). FRP bathtub manufacturing waste was fed in the experimental plant together with water and an alkali catalyst, and a sub-critical water hydrolysis reaction was conducted at 230° C and 2.8 MPa. In spite of 10,000 times difference in the test scale between the reaction pipe and the experimental plant, the test showed a successful scale-up demonstration. Fig.7: Experimental plant for subcritical water hydrolysis Fig.6: Modification of the styrene-fumaric acid copolymer SMC (sheet moulding compound) sheets were produced with the SBFC and the commercial LPA comprising polystyrene, inorganic filler and glass fibre to evaluate the shrinkage control effect. After cure of the SMC sheet, the shrinkage ratio of the FRP board sample was evaluated. The results showed that the SBFC’s shrinkage control effect is almost equivalent to the commercial LPA (Table 2). The market price of commercial LPA is 5 to 10 times higher than that of styrene. The results suggest that the SFC was regenerated to such high-value-added materials after recycling. Industrially speaking, the process can be called “enhanced recycling” because the materials can be recovered and renewed to a much greater extent than in more sophisticated applications such as LPA. Tab.2: Results of the shrinkage control effect evaluation An experimental plant for inorganic material separation using the filter press method was also built. The experimental testing of the inorganic material separation process is shown in figure 8. The recovery rate of the reaction liquid and inorganic materials was 90 wt% and 95 wt%, respectively. The recovered inorganic materials were used as recycled inorganic filler to produce FRP samples to be compared with the FRP sample made from new raw materials. Their strength characteristics were evaluated. The FRP sample with recovered inorganic materials showed equivalent strength characteristics to the FRP sample with new raw materials. Additive Compounding ratio Shrinkage ratio No additive Commercial low profile additive Styrene-benzyl fumarate copolymer 0wt% 0.338% 1.0wt% 0.196% 1.0wt% 0.202% Fig.8: Experimental testing of inorganic materials separation Experimental testing of sub-critical water hydrolysis and inorganic materials separation An experimental plant with a capacity of 40 kg FRP per operation was built for the sub-critical water hydrolysis Conclusion In a reaction at 230° C for 4 hours with potassium hydrate, the thermosetting resin was almost perfectly dissolved and 71 wt% of the initial glycol and 22 wt% of the initial fumaric JEC Composites Magazine / No40 May 2008

JEC COMPOSITES MAGAZINE - Issue #40 - May 2008

Table of Contents for the Digital Edition of JEC COMPOSITES MAGAZINE - Issue #40 - May 2008

Cover
Edito
NEWS WORLDWIDE | Companies
Nippon Graphite Fiber increases production capacity
World’s largest ECR glass fibre plant
CPIC and Abahsain set up glass fibre joint venture
Airbus negotiations called off in Germany
A400M static testing
Agenda of events
Equipment: non destructive control
BUSINESS
Market survey: India
Trends | Two major sustainable development challenges: raw materials and energy
Niche market | Taking up the rapid manufacturing challenge
Human capital |Choosing the right opportunity
FEATURE | Wind energy : Market update
History : Not just another windmill story
Process : An experimental vertical-axis wind turbine system
Composite manufacturing process for wind energy
Materials technology for the wind energy market
Equipment : The perfect mixture
USERS’ PLATFORM
Composites in the world : Bamboo helmet
Very exclusive business cards
World’s First Integrated Wind Turbines
Solar energy and hydrogen powered plane
Successful partners : Art nesting in a composite bower
Applications : A Hybrid composite carbody for korean tilting train
KNOW-HOW : Environment
Coupling agent : Composite stone
Process
Bonding : INDAR
Special Asia
News
Application
Products from exhibitors
Participating companies
Singapore today
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Cover
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 2
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Edito
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 4
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 5
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 6
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 7
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - CPIC and Abahsain set up glass fibre joint venture
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - A400M static testing
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Agenda of events
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 11
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Equipment: non destructive control
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - BUSINESS
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Market survey: India
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 15
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 16
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 17
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Trends | Two major sustainable development challenges: raw materials and energy
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 19
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 20
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 21
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Niche market | Taking up the rapid manufacturing challenge
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 23
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Human capital |Choosing the right opportunity
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 25
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - FEATURE | Wind energy : Market update
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 27
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 28
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - History : Not just another windmill story
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 30
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Process : An experimental vertical-axis wind turbine system
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 32
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 33
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 34
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 35
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 36
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 37
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Composite manufacturing process for wind energy
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 39
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 40
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Materials technology for the wind energy market
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 42
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 43
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Equipment : The perfect mixture
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 45
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 46
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - USERS’ PLATFORM
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Very exclusive business cards
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Solar energy and hydrogen powered plane
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Successful partners : Art nesting in a composite bower
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 51
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Applications : A Hybrid composite carbody for korean tilting train
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 53
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 54
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - KNOW-HOW : Environment
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 56
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 57
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 58
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 59
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Coupling agent : Composite stone
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 61
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Process
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 63
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 64
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Bonding : INDAR
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 66
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 67
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 68
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Special Asia
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - News
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - III
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Application
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Products from exhibitors
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Participating companies
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - VII
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Singapore today
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