JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 56

KNOW-HOW Environment FRP recycling technology using sub-critical water hydrolysis A thermosetting resin for FRP was optimally hydrolyzed to glycol and a styrenefumaric acid copolymer (SFC) using sub-critical water. The modified SFC showed an equivalent performance to a commercial low-profile additive. This process is now being proposed for enhanced recycling. TAKAHARU NAKAGAWA, GENERAL MANAGER ADVANCED TECHNOLOGIES DEVELOPMENT LABORATORY MATSUSHITA ELECTRIC WORKS, LTD. I n Japan, fibre reinforced plastics (FRP) are widely used for many products such as bathtubs, boats, tanks, and so on. However, they are considered as extremely difficult to recycle satisfactorily, since their constituent thermosetting resin cannot be re-formed after the final cure. The total amount of FRP waste reaches 400,000 tons annually and, as it happens, most FRP waste is landfilled in Japan, leading to wasteful use of limited oil resources. To reduce the amount of waste and utilize exhaustible oil resources more efficiently, these materials (including thermosetting resins) should be recycled, which would be more conducive to a sustainable society. The thermosetting resins used in FRPs are a cross-linked styrene polymer (as cross-linking agent) and unsaturated polyester. In general, the unsaturated polyester is a condensate polymer consisting of glycol and maleic anhydride. They are condensed to form ester bonds through dehydration. It is known that maleic anhydride changes from malete (cis) to fumalete (trans) through the condensation. After hot-press curing, styrene cross-linking is developed. Several FRP recycling technologies, such as thermal recycling methods using high-temperature and high-pressure water, the cement kiln method, and the chemical method using glycol or benzyl alcohol, have been implemented in Japan. However, there is no effective method available to recycle FRP materials along with the thermosetting resin. We have been developing an FRP recycling technology using subcritical water hydrolysis since 2002. Sub-critical water is hightemperature, high-pressure water that is known to have a significant hydrolytic capability due to its ion product and dielectric constant. Its advantage over other chemical recycling approaches is that it breaks ester bonds more effectively. Our research aims at establishing an effective horizontal recycling technology that includes thermoset resin so as to solve the environmental issues mentioned above and as shown in figure 1. Fig.1: Overview of the FRP recycling technology using sub-critical water hydrolysis FRP recycling technology using sub-critical water hydrolysis With the FRP recycling technology using sub-critical water hydrolysis, the thermosetting resin can be recycled into basic materials with a material recycling rate of 70%. Moreover, with horizontal recycling, the FRP including the thermosetting resin can be recycled back into FRP (e.g. the old FRP bathtub into a new one) and the thermosetting resin portion of the waste can be recycled into high-value-added materials (enhanced recycling). Fig.2: The concept of sub-critical water recycling of thermosetting polyester resin JEC Composites Magazine / No40 May 2008

JEC COMPOSITES MAGAZINE - Issue #40 - May 2008

Table of Contents for the Digital Edition of JEC COMPOSITES MAGAZINE - Issue #40 - May 2008

Cover
Edito
NEWS WORLDWIDE | Companies
Nippon Graphite Fiber increases production capacity
World’s largest ECR glass fibre plant
CPIC and Abahsain set up glass fibre joint venture
Airbus negotiations called off in Germany
A400M static testing
Agenda of events
Equipment: non destructive control
BUSINESS
Market survey: India
Trends | Two major sustainable development challenges: raw materials and energy
Niche market | Taking up the rapid manufacturing challenge
Human capital |Choosing the right opportunity
FEATURE | Wind energy : Market update
History : Not just another windmill story
Process : An experimental vertical-axis wind turbine system
Composite manufacturing process for wind energy
Materials technology for the wind energy market
Equipment : The perfect mixture
USERS’ PLATFORM
Composites in the world : Bamboo helmet
Very exclusive business cards
World’s First Integrated Wind Turbines
Solar energy and hydrogen powered plane
Successful partners : Art nesting in a composite bower
Applications : A Hybrid composite carbody for korean tilting train
KNOW-HOW : Environment
Coupling agent : Composite stone
Process
Bonding : INDAR
Special Asia
News
Application
Products from exhibitors
Participating companies
Singapore today
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Cover
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 2
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Edito
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 4
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 5
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 6
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 7
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - CPIC and Abahsain set up glass fibre joint venture
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - A400M static testing
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Agenda of events
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 11
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Equipment: non destructive control
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - BUSINESS
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Market survey: India
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 15
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 16
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 17
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Trends | Two major sustainable development challenges: raw materials and energy
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 19
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 20
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 21
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Niche market | Taking up the rapid manufacturing challenge
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 23
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Human capital |Choosing the right opportunity
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 25
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - FEATURE | Wind energy : Market update
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 27
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 28
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - History : Not just another windmill story
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 30
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Process : An experimental vertical-axis wind turbine system
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 32
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 33
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 34
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 35
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 36
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 37
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Composite manufacturing process for wind energy
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 39
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 40
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Materials technology for the wind energy market
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 42
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 43
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Equipment : The perfect mixture
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 45
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 46
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - USERS’ PLATFORM
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Very exclusive business cards
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Solar energy and hydrogen powered plane
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Successful partners : Art nesting in a composite bower
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 51
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Applications : A Hybrid composite carbody for korean tilting train
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 53
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 54
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - KNOW-HOW : Environment
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 56
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 57
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 58
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 59
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Coupling agent : Composite stone
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 61
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Process
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 63
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 64
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Bonding : INDAR
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 66
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 67
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - 68
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Special Asia
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - News
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - III
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Application
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Products from exhibitors
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Participating companies
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - VII
JEC COMPOSITES MAGAZINE - Issue #40 - May 2008 - Singapore today
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